Corn quality, mashing, fermentation, distillation, coproducts—each
year The Alcohol School provides a comprehensive course on making
ethanol efficiently. In September, 90 participants flew into Montreal
for the 32nd annual school, which digs into the science behind the
process as well as new developments under way for both the fuel ethanol
and beverage alcohol industries. The cross fertilization is deliberate,
not only between the beverage and fuel alcohol producers, but also for
related companies that send employees to get a broader understanding of
the industries served. Ethanol Producer Magazine attended this year and
gives a taste of what was learned, with a focus on areas with a big
impact on the bottom line in the initial steps of the process.
“If
you want to save money, improve your bottom line in the biggest
cost—feedstock,” said Robert Piggot, technical consultant with Lallemand
Ethanol Technology, a co-sponsor of the event with the Ethanol
Technology Institute.Promotional custom keychain
at ePromos Promotional Products. When buying corn, ethanol producers
are most interested in the starch. Nonetheless, a survey of ethanol
producers once asked if they would pay more for corn if they could get 3
percent more starch. “Most ethanol plants said no,” he said. For a 100
MMgy plant, that 3 percent would add up to $13 million more revenue, if
ethanol were selling at $2.50 per gallon, he pointed out.
There
can actually be a conflict in the goals between the purchasing
department, which is looking for low cost, large quantities and flexible
payment terms, and operations, which needs easy-to-process, high
yielding corn to be delivered on a timely basis. Operations is looking
for high starch content, low moisture, high ratios of
amylopectin-to-amylose and floury-endosperm-to-horny-endosperm, and no
molds or mycotoxins, which means the standard grade of No. 2 yellow dent
corn isn’t all that helpful. “We are stuck with the specifications that
were meant for the baking and feed industries, and they actually don’t
mean anything to us,” Piggot said. Broken kernels,Carlo Gavazzi offers a
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for instance, could be considered beneficial for the ethanol industry,
while foreign material wouldn’t. Thus the maximum 3 percent BKFM is not
specific enough. No. 2 specs also call for a 5 percent maximum in
damaged kernels,Find the best iPhone headset
for you at Best Buy. with no more than 0.2 percent heat damaged. “If
the grain is heat damaged, you lose sugars,” he explained. “Other types
of damage are not a problem.” The moisture spec of 14.5 percent is
well-understood, but the test weight spec of 54 or 56 pounds per bushel
is meaningless, he said. “You often get better yields out of low test
weight corn.”
Piggot recommends plants make their expectations
clear when explaining their quality needs and setting discounts. “You’re
better off to discount the grain,” he added. “Try not to get into the
loop of getting a rejected load returned to you, just blended up.”
Discounts need to consider hidden and indirect costs. High moisture
corn, just 1 percent over the 14.5 percent spec, would translate into a
direct cost of 50 gallons of ethanol lost from the load, which at $2.50
per gallon ethanol, would call for a discount of 16 cents per bushel. He
recommends that number be doubled to account for other increased costs.
For example, the electrical power needed to grind wet corn will be
significantly higher than for properly dried corn.
Attention to
details in grinding corn is the next area that can have a direct impact
on yield. The ideal grind size is very much plant-dependent, Piggot
said. While there are advantages to smaller grind sizes that increase
the surface area exposed to enzyme action, problems can arise. Factors
to consider include how well the slurry mixes and temperature
parameters. Coarser grinds need slightly higher temperatures while finer
grinds are needed if jet cooking is not used. Finer grinds will keep
suspended longer in the fermentor, but will contribute to quicker
fouling in the stripper and heat exchangers, plus impact centrifuge
separation. The goal is to get the best compromise of particle size for
maximum yield and good separation—too large and yields are lost,Offering
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Most
ethanol plants use hammermills to grind, and many never take a close
look at the configuration, Piggot added. A number of things can be
adjusted to improve performance, including the speed and number of
hammers as well as spacing, plus the open area on the screen, feed rate,
air flow and hammer-to-screen distance.
The next step in the
process, mashing, is also a key area for maximizing yields, said Garth
Whiddon, technical service manager for Lallemand Ethanol Technology. In
mashing, water is combined with the crushed or ground grain, adjusted
for pH and temperature to match the chosen enzymes used to break the
starches down into dextrins. “Having the optimal conditions for
enzymatic efficiency leads to lower usage rates and higher yields,” he
said.You'll be able to spot your bag from a mile away with these elegant
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Fine tuning this step is important. If 4.5 percent residual starch is
left after fermentation, it adds up, amounting to $2.6 million lost for a
50 MMgy plant.
The industry has gone through some major process
changes, Whiddon added. At one time, nearly every plant used a separate
saccharification tank, where the mash was cooled before adding
glucoamylase. While it may have been optimal for the ideal enzyme dose,
it also created a perfect environment for bacteria. Most plants have now
moved to simultaneous saccharification and fermentation.
A more
recent process change has been a move towards dropping the jet cooking
step. In addition to decreasing enzyme use by nearly 25 percent,
eliminating jet cooking prevents a possible 3 to 5 percent yield loss
from a Maillard reaction—a chemical reaction that makes some sugars
unfermentable and also reduces the free amino acids needed for yeast
health. If jet cooking is eliminated, however, the grind requirements
are more stringent, he adds, to ensure proper starch conversion.
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